• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Fertilizers coated with coating layer having a controlled moisture permeability and a controlled temperature dependency of moisture permeability are presented by the production method which comprises ejecting hot drying air to the spout of granular fertilizer and spraying a hot solution of polyolefin type resin, ethylene-vinyl acetate copolymer or vinylidene type resin upon said fertilizer granules and drying said fertilizer granules upon being sprayed with solution having the property capable of forming a solution while it is hot but turning into jelly-like gel when it is cooled but as a most characteristic feature of this method uniformly dispersed fine powder is incorporated in said drying air or in said solution so as to have a coated layer of said resin containing uniformly distributed fine powder.
    公开号:SU1528342A3
    申请号:SU782649301
    申请日:1978-08-07
    公开日:1989-12-07
    发明作者:Фудзита Тосио；Такахаси Тиго；Есида Сигемицу；Симизу Хирозо
    申请人:Чиссоасахи Фертилизер Ко., Лтд (Фирма)；
    IPC主号:
    专利说明:

    Ahi li pT; iiIH i ;; j: K:
    (21) 2649301/2: V-2fi
    (22) 07.08.7I (W) 98) / 78 (32) 09.01 LA (33) (46) 07. 2, JAC, UKPI.
    (71) Chissoa. Co., Ltd. (,
    (72) Tosnr ud ita, TNG (1 Takah si, Sigemill and XHIV ;; (; C / ig-pg; I J O
    (53) 631, a42, Ai 088.8 i
    (56) Pat mg-IT g 15E2566, cl. Since OS 1/00, 1972,
    (54) METHOD FOR GETTING THE ULIROVA HI / UBRANCH WITH THE OTHER SPEED YYLET WITH THE OWN SPEED) 1 NITCH
    (57) The invention relates to the technology of popu rapy. Pyrone au 1 y. fertilizers of prolonged action and may be used for the manufacture of fertilizers with controlled release of nitrogen. From the pellet it is possible to regulate the temperature dependence of the velocity of solution; . G.Ch 1; - I; in, -G I.
    1 o r-g; (and i i
     f:: ii h.psp; ::.: :: I -HUpriv l, ---; - ;; (-. t,::. ь; iipiii g; s; 10P (: diglk g -ptn- I -: - MJ nilKHJi MCH i njlbHb fi llCl OlIinK - Ch gr -, - .. 11ı, iur; -: nv) i. I::; "- 1--;,:;,,. I y- -.:-. ivp - i sufi. dilt: - GOPPYA; lm. |; n) - c (IG-CT1, G
    o, l - Li;.; to the quantity; .ag. b,; 1 mole n 1: |, 1Л | tm 1-. jircTBopa in the form of cf. Lm esky PL - -; . ifHTeJ- - i - that, --- hloggggli) with i H; iivOCTb fi not more than 40 ET1, Sm.lu and 1 orochk spyl yy gran-t T, norie.pxiTPCTH; --r KTi P
    Hhi: -1 T. jnieC7 ROM - OK. OKCI- T.L.CH
    nyiky ililormm iipoc biv ether or 1 ek with i о. And style - and-m skschlfen poplm nros- TbiM: Lire f.i-i with a tune and PAR 1, 0 (OsOOi-O OOS). 1 h li f-hgy, 2 silt, 5 tlo.p ..
    The invention relates to a technology for producing granular fertilizers of prolonged action and can be used in the preparation of fertilizers with controlled release of nitrogen.
    The purpose of the invention is to make it possible to control the temperature dependence of the dissolution rate of the nitrogen-containing component of the fertilizer,
    An example. The method of obtaining coated granular fertilizers
    OS: / 1ISSS1RLA} FROM at D 1SPERGIROB, PP g
     powder in solution, Alparg for the coating of the type of pemeyayuyu PGG Og has a flow rate of i – i; iri-meter 250 mg and a height of 2000 mm, the diameter of the wall is 50 mm, and OO The flow of air passes through to the 4-11: 01 part of the flow-through kolg-yin; with f, the power of 1 rrntil torr (air blower) of the external cut-off device is determined; speed flow and heat pumping K, K..iches sun pg V: seh duhudy regulation ;;: - um
    as a measure for air, and the temperature is regulated by a heat exchanger, the exhaust air flows through the inlet for the exhaust air leaving the column. The granular fertilizer to be treated for the coating comes from the fertilizer inlet to the column by passing hot air through it under appropriate conditions to form a stream. When the particles in the column reach 70 ° C, the resin coating solution is blown into the stream as a spray jet through a flow nozzle. The resin solution is fed through a pump from the solution tank, where mixing is carried out using a stirrer, into the nozzle. A temperature maintenance device maintains the temperature of the resin solution at a set value. When the coating reaches a certain value (%), the fan is turned off, and the resulting product is removed through the loading hole. In addition, the temperature of the hot air, the temperature of the particles and the temperature of the outgoing air are determined respectively with thermometers T, T 2 and T .
    The basic conditions of the example are as follows: a flow nozzle (opening degree 0.8 mm) of a conic type of Fulla; the amount of hot air is And m / min; hot air temperature of 100 ° C; fertilizer - spherical particles of urea (5-7 mesh); amount of fertilizer 10 kg; amount of supplied solution 0.5 kg / min
    The resins used in this invention as the main component of the resin part of the composition include polyolefin type resin: polyethylene, polypropylene, polystyrene, ethylene-vinyl acetate copolymer, vinylidene copolymer — vinyl chloride, and a combination of the above components.
    The fine powders according to this invention are such powders that form voids within the coating layer: talc, silica, diatomaceous earth, iron and aluminum oxides, calcium carbonate, and the like. Most preferred of
    HVix is talc due to its bolué of light dispersive wear. The particle size is in the range of 0.01-40 µm, preferably 0.1-20 µm. If the dimensions are frequent; exceed the specified interval, the concave elements can not be covered with a film of resin, for a complete coating should be created a thicker film coating. If the particle size is less than 0.01 µm, then a porous coating of ne is obtained. The solvent is tetrachlorethylene
    5 (kip, 21 s), resin, fine powder, etc. in specified quantities, is fed into a container for dissolution, the temperature is raised to 110 ° C, dissolution is carried out with stirring scientific research institute to obtain a solution for coating. The supply of materials is carried out under stirring to uniformly distribute fine powder.
    5 spreads, powder is given but delivery time, preliminary tests are carried out in advance to prove the constant concentration of the powder in the solution with time and whether such concentration is maintained at a constant level.
    In tab. Figure 1 shows the conditions for preparing the samples obtained in this example and the degree of dissolution of the samples (%) when they are placed in water at 25 ° C for 24 hours. Each of these samples retains the ability for slow release.
    Each sample is cut into sheets using a knife, the resulting materials, dried after complete dissolution of the urea contained inside them, are packed into cylindrical filter paper and then extracted with tetrachloroethylene as a solvent in a Soxhlet extractor to determine the amount of talcum, based on the filter paper and the amount of resin obtained by evaporation of the extract to dryness, the research results confirm the composition of the resulting capsule;
    5 The formation of voids in the porous coating varies depending on the amount of fine powder added. If its quantity was 0
    five
    0
    five
     It is less than 30 May, 7 ,, then there is no formation of voids. When the amount thereof is 40% by mass or more, the number of voids increases with an increase in the amount added. The resin solution forms the solution form in a state that chokes off the finely divided component of the resin upon cooling the solution, a yellow gel is generally formed, in which the resin component is uniformly distributed. Thus, if the condition of instant drying of the solution is not bold from the granules of fertilizers, then a homogeneous film porous coating is not formed.
    Example 2. Applying nailing with dispersigropanin of a thin heel in air for 24 hours. Diffusion of the coating according to primer 1 means that the device for the substitution of fine pacnoj.o.iKeKc powder in front of the heat exchanger, the powder in a given amount comes through the device, so that the time of its subfire may correspond to the time of supply of the solution for coating the Reasons ;; the fact that the device for feeding fine porO1 is located on the front of the heat exchanger closes the dispersion capacity of the fine powder and the air obtained by using such a device and its location is not essential for obtaining good dispersion.
    In tab. 2 The results of the preparation used in this example, as well as the percentage of excretion in the aqueous solution at 25 ° C, measured after 24 hours. Although there are deviations in the percentage of coating, each of them has a slow release of fertilizer. In addition, the ratio of the resin to the powder in the capsule prepared in accordance with Example 1 is determined and the composition is confirmed.
    Example 3 Confirmation of the formation of voids by the addition of a fine powder. In this example, it is proven that the capsule of the invention has voids inside it. The sample obtained in Example 1 is cut with a knife, and the AGM is placed in water to dissolve the urea containing it and dried with air. Tetrachloride
    52834

    and mnjioBLiri cnjipT; chilled / up to
    about about:
    er 1., mixed in different cooTHoiiieHn-x with obtaining a series of property in,. the weight of which is supplied as Oi92-1 .6 g / ml. The specific dog of the cootted cut pieces is measured with l mt with Ml, -1 and with a and n i. | M etto d dm,
    T loji, 3 sog rr. r-i Rt-; a (L | 1s: cho -,} h;
    , :: tl;.; TPTOV) peIIP
    Gg / G; To: PG -;. R-chii ii -: -i .inr; -:
    KniiOlTK p2 s SFN LIPNO that k .I J. i C
    no .ieuHi-- talc (n} c-BE1 I L: T ;;
    n-4JM.-CTb wg P: PGT SG SG LF
    M1.ch1ichi ets l Rel-shsig. . gtpt y;. (- npts naets, Kp-v-fp toge, ptn.
    O hOHn K tgL - nOnV4-inT rG ULTP G hl;). . I iMX is an LR; - and; . R | ;:: m hch-sdii: in.v oju u: ci: i-i smopes hll.r.n
    Г; п-1 COrT j: i: r:; .- v 1 / р, Ь-; oi K::. iii -; (CTHJ-imi iT Y: i Y, nn:, i; n ..ii3c nyc f OT; 1ychi :: - m1 no
    1 / p, 1 / p5.
    V - п ... П chinl rychis: i-1: I am a general, ,, leverage: h: -it; п i, p.
     - V /,;,,,. " one

    rr, - .: I p
    vAe: ibHh f IUK; (sr: 0.93 g / ml);
    Dec)} ht1 | Yea
    2.8 - / chg),
     or
     (:
    H.i .si nej; v i-Mjii;
    ; and
    GTSHCHKMMG -,.,
    And; , MO0
    five
    oi n t a: -1;. floor cpt1 I1 rp p | ; i; Hoi o ratio CMoni.i and tspk-g Kg). Ri; i uvegtich; nip ciTtirriojU q ncipr Ji; p number of T vrTrr tpk, -: ugg leans out - and dissociation from the mouth of i rstnog itts less chuvstr -: rt) :) to ow; 1 1T; ri, .. with isolcio: (An11 and only gmoles of igi G-Cr-ly and fine powder t kgmgy igthr or less O, p, a; tc; rk- - there is no occurrence of fuzz. Temperature dependence ; pgm; -t1, vyzleri from the solution VM c-ni -; ib; i- EL, Pr :. that case 1-: depe1 AND (-m t-an-faith changes when G: ernr - - ::, - :
    7
    when the temperature rises every 10 ° C. Irie mixing a fine powder; obtaining a maximum amount of 80% by weight, the release of the Hs solution varies by about 1.9 times, and the effect of temperature gives the minimum value. Thus, in the above range of values, it becomes possible to control the release rate from the solution.
    In addition, by adding fine powder, capsule properties can be significantly changed. Capsule strength tends to decrease markedly. For example, adding 50 wt.% Fine powder, such as talcum, and as a filler for a polyolefin resin, and when producing a film from a melt in an extruder, the strength hardly changes, but in the case of the present invention, the strength decreases by about 1/5. This is because in the case of conventional molding, fine powder and resin stick to each other very firmly, but in the case of the product of the invention, a large number of voids are formed. This is a rather important property, since the remainder of the capsule after use is susceptible to raelization (and can turn into a soil structure. If powder is added, there is a tendency that with an increase in the quantity being mixed, release from the solution is accelerated. As for the resin, if desired reduce the rate of its release from the solution by increasing the amount of mixed fine powder, i.e. if you want to reduce temperature dependence, then you need to choose just one resin or use a combination with nshey moisture permeability. Said feature allows to obtain fertilizers with different release rates from solutions with various fertilizers and dependence You are a de.cheni from solutions by adjusting komOinatsii fine powder and resin.
    Example 4. This example illustrates the effectiveness of the dependency. bridges the temperature of the rate of release of nutrients from the solution. Each sample weighing 10 g is introduced into 200 ml of water and after a certain period of time it is kept
    five
    0
    five
    283428
    They are fed at a certain temperature, then comppiept is analyzed. excreted from aqueous rastporl, according to the usual method, and determine the degree of discharge of ich solution. The solution for dissolution is updated in each assay, the analysis is continued until the determination of the rate of separation from the solution with respect to the supply, the time duration, and the curves are made for such release rates from the solution
    FIG. 1 shows the curves at different temperatures measured for the sample of Test 1 of Example I; in fig. 2 - the length of time in days, necessary to achieve the release of nutrients from the solution, amounting to more than 80% by weight, at a low temperature level.
    Increasing the temperature by 10 ° C increases the rate of separation of the p-solution by about 2.5 times. This ratio can be expressed as Q, o 2.5. Thus, Q, d of each sample are measured, which are summarized in Table. D. The effectiveness of this invention is evident from the fact shown in Table. And where, with an increase in the amount of talc added, the effect of temperature becomes less.
    Some trials are conducted in relation to the samples obtained in Example 2, which confirm that the effect of temperature can be controlled in cases where any fine powder is used in a manner similar to Example 1.
    From the data table. 1-4, it follows that the temperature dependence of the rate of nitrogen release (Q) can be regulated not only by the amount of mineral powder, but also by the amount of surfactant and the resin: surfactant ratio, which remains constant and is 1 : 0.001.
    Example 5 (ps of the invention). A resin-coated urea is prepared containing 40 May.52 polyethylene and 60% by weight talc according to the procedure described in Example 1, and the percentage of separation from the aqueous solution is determined, while the release time of 80% by weight of nitrogen from the solution at 25 ° C is 188 days, and Q ,, 2.09, It shows such.
    0
    five
    0
    five
    0
    five
    the degree of separation from the solution, as in the sample during the experiment I, but the temperature dependence is improved, as shown in table. five.
    According to the present invention, it is possible to obtain a coated 1 fertilizer with various rates of release from a solution and with a desired prepreparation and temperature dependence. Covered granular fertilizers absorb soil moisture through the covering film due to the pressure difference of water vapor. The fertilizer located inside the capsule absorbs moisture, liquefies, and some of them dissolve to form a solution. By accepting a large amount of moisture inwards, the internal, i.e. osmotic, pressure rises. In addition to the stresses generated by this osmotic pressure, the effect of the means forming the punctures of the surfactant of suitable molecular weight creates salt discharge openings.
    The removal of the fertilizer component from the solution is partially carried out by concentration diffusion, but mainly by dissolving in a stream of water that passes inward through the covering film and flows out of the discharge openings. Therefore, the rate of release from a solution is most affected by the penetration of a certain amount of water vapor. The reason why the release from the solution of the coated granular extrac tion largely depends on the temperature lies precisely in this moment, since an increase in temperature increases the difference in pressure of water vapor outside and inside the resin capsule exponentially, and an increase in temperature further increases moisture permeability.

    34210
    The film itself, These two E |}) effects are combined, which contributes noBt.niie to the moisture permeability of the resin capsule to a rather large extent, while the prototype temperature dependence of nitrogen excretion from fertilizer is not observed.
    权利要求:
    Claims (1)
    [1]
    Invention Formula
    . A method of producing granulated fertilizer with a controlled rate of nitrogen release, including the deposition of a coating layer formed of a polymer-type resin with dispersed fine mineral powder i, by spraying the resin solution onto the surface of the granules in a stream of hot air, characterized in that controlling the temperature depending on the rate of dissolution of the nitrogen-containing component of the fertilizer, the resin is selected from the group of: polyethylene, polypropylene, polystyrene, ethylene copolymer with video vinyl acetate, vinylidene chlorophenol copolymer with vinyl chloride or their mixture, and mineral powder selected from the group: talc, and Al 2 O 3, calcium carbonate, silicon dioxide, diatomaceous earth, powder used with a dispersity of 0.01-40 microns in an amount of 40-80 wt. %, and the resin is sprayed as a solution in tetrachlorethylene (organic solvent) with a viscosity of not more than 40 centipoise.
    2 o The method according to 1, characterized by the fact that the said resin and mineral powder are sprayed onto the granules together with the octo-ethylene-n-nonylphenyl ether or hexoxyethylene-n-hexylphenyl ether, surfactant when the ratio of resin to surfactant in the range of from 1.0: 0.001 to 1.0: 0.005 by weight. C1 - ol - a mixture of 60% of low-density polyethylene with 40% of a copolymer of ethylene with zinic acetate.
     Talc - particle size 1-20 90%; specific gravity 2.8 g / ml. The surfactant substance is n-choiphenyl octo-oxyethylene ester,
     : -ol | Ch pnn iisheikhlorkcha with pinnylhlppid. Psl1: h gklen and polystyrene), rarnnp.-NiujfH, - Pplkprokpenen with slalkmer winnitetatz with ztileno (l: i) i PAR for dl examples 20-25 - hexaoxylt
    n rt Krftji (eni -ffr, uloren; thawed A and karjondt calcium have almost such acTHUj size as
     in tpbl. ; tshk V n silica B - sizes of the particles interval num μm 90Ilj time of pebbles B
    g, cr: μc h — For 30 minutes minus 20 MU1 for the case of other articles, STDM case1. is reached
     f i I i rte Rppshe what roAfUOT is W1 kolnchesteoO solution, to K 9 prnmeuy I, that is, 0.5 kg / nii.
    t. 1 about l and II-I 2
    SO
    (
    /
    V
    -g
    X
    h: l
    t
    G9SH
    / sh
    . ;; P - L .f.i
    r, f
    /
    25 С
    755.
    ,
    t7 6
    t
    four
    类似技术:
    公开号 | 公开日 | 专利标题
    SU1528342A3|1989-12-07|Method of producing granulated fertilizer with controllable nitrogen release rate
    SU1241984A3|1986-06-30|Method of producing slow-acting granulated fertilizer
    US4881963A|1989-11-21|Granuler fertilizer with a degradative coating
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    US4023955A|1977-05-17|Controlled release fertilizer
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    JPH11512019A|1999-10-19|Apparatus and method for coating solid particles
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    US4391920A|1983-07-05|Porose, pulverformige polymerteilchen
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    US3227789A|1966-01-04|Process of pelletizing a water soluble material
    JP2000053481A|2000-02-22|Mixed fertilizer containing coated nitrification suppressor
    US3445283A|1969-05-20|Process for the preparation of instantaneously soluble,porous granular sugar
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    US3143460A|1964-08-04|Method for making pesticide composition of a pesticide-resin mixture coated on granules
    CS268502B2|1990-03-14|Process for pelletising and granulating ammonium sulphate
    KR910008475B1|1991-10-18|Fertilizer with a degrative coating
    AU624413B2|1992-06-11|Method of preparing granular culture soil
    US3023252A|1962-02-27|Calcium trimethylolphenate
    同族专利:
    公开号 | 公开日
    GB2011367A|1979-07-11|
    US4369055A|1983-01-18|
    JPS603040B2|1985-01-25|
    CA1111277A|1981-10-27|
    DE2834513A1|1979-07-12|
    JPS5497260A|1979-08-01|
    DE2834513C2|1983-11-17|
    GB2011367B|1983-01-12|
    IT7826546D0|1978-08-07|
    IT1111674B|1986-01-13|
    LU80085A1|1979-01-19|
    NL176448B|1984-11-16|
    FR2413932A1|1979-08-03|
    AU3901178A|1980-02-21|
    NL176448C|1985-04-16|
    NL7808231A|1979-07-11|
    BE869577A|1978-12-01|
    AU520642B2|1982-02-18|
    FR2413932B1|1982-03-19|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3372019A|1964-09-28|1968-03-05|Chevron Res|Slow-release coating composition consiting of wax and ethylene vinylacetate|
    DE1592655C2|1966-07-13|1972-03-30|Gewerkschaft Victor, Chemische Werke, 4620 Castrop Rauxel|Fertilizer granulate with controlled nutrient release|
    FR1591081A|1968-09-06|1970-04-27|
    US4015970A|1968-09-06|1977-04-05|Airwick Industries, Inc.|Granular products for soil treatment|
    DE2021259C3|1970-04-30|1979-02-08|Gewerkschaft Victor Chemische Werke, 4620 Castrop-Rauxel|Fertilizer granules with controlled nutrient release|
    JPS543104B2|1973-12-28|1979-02-17|DE3203849C2|1982-02-02|1991-10-10|Schering Ag Berlin-Bergkamen, 1000 Berlin, De|
    KR890015981A|1988-04-06|1989-11-27|모리 히데오|Coated Granular Fertilizer Composition and Method for Making the Same|
    JPH0587480B2|1988-10-19|1993-12-16|Central Glass Co Ltd|
    US5030267A|1988-11-14|1991-07-09|Nutrihold Inc.|Method of preparing controlled release fertilizers and products thereof|
    WO1990010691A1|1989-03-10|1990-09-20|Grace-Sierra Horticultural Products Company|Tissue culturing|
    US5264019A|1991-03-05|1993-11-23|Eastman Kodak Company|Coating compositions for slow release fertilizer formulations|
    US5228895A|1991-04-11|1993-07-20|Kelly Lime And Rock Company, Inc.|Fertilizer and limestone product|
    US5652196A|1991-07-22|1997-07-29|Oms Investments, Inc.|Timed release of water-soluble plant nutrients|
    DE4127459C2|1991-08-20|1993-07-29|Aglukon Spezialduenger Gmbh, 4000 Duesseldorf, De|
    TW210995B|1991-09-19|1993-08-11|Asahi Chemical Ind|
    US5211985A|1991-10-09|1993-05-18|Ici Canada, Inc.|Multi-stage process for continuous coating of fertilizer particles|
    US5560768A|1993-05-06|1996-10-01|Haifa Chemicals South Ltd.|Method for preparing an encapsulated slow-release particulate fertilizer|
    EP0701543A4|1993-05-07|1997-10-22|Univ New England|Improved fertilizer coating process|
    JP3291077B2|1993-07-21|2002-06-10|旭化成株式会社|Multi-layer coated granular fertilizer consisting of coating materials with different decomposition rates|
    MY121922A|1993-09-21|2006-03-31|Exxon Res & Engineering Company|Bioremediation of hydrocarbon contaminated soils and water.|
    US6503288B1|1996-12-30|2003-01-07|Bayer Corporation|Process for the production of biodegradable encapsulated fertilizers|
    JPH10212205A|1997-01-29|1998-08-11|Chisso Corp|Time interval release type coated agrochemical granule|
    EP0976699A4|1997-02-19|2009-06-03|Chisso Asahi Fertilizer|Granular fertilizer coated with decomposable coating film and process for producing the same|
    US6045810A|1998-04-27|2000-04-04|Agri-Nutrients Technology Group, Inc.|Reinforced-resin coated plant food granules|
    US6001147A|1998-07-23|1999-12-14|Bayer Corporation|Unsymmetrical polyureaurethane fertilizer encapsulation|
    US6152981A|1998-07-23|2000-11-28|Bayer Corporation|Sulfur containing isocyanate compositions|
    US6165550A|1998-07-23|2000-12-26|Bayer Corporation|Symmetrical Polyurea-urethane fertilizer encapsulation|
    FI107024B|1999-06-14|2001-05-31|Kemira Agro Oy|Method for coating particles, use of coating suspension and coated product|
    US6364925B1|1999-12-10|2002-04-02|Bayer Corporation|Polyurethane encapsulated fertilizer having improved slow-release properties|
    JP2002068880A|2000-06-14|2002-03-08|Chisso Corp|Coated bioactive granular material and method of manufacturing for the same|
    US6358296B1|2000-07-11|2002-03-19|Bayer Corporation|Slow-release polyurethane encapsulated fertilizer using oleo polyols|
    EP1199291A1|2000-10-17|2002-04-24|Agra Dünger GmbH|Coated chemical product and process for making the coated chemical product|
    US6617412B2|2001-10-12|2003-09-09|Bayer Corporation|Fertilizer encapsulation using sulfur containing polyols|
    KR100961030B1|2005-04-07|2010-06-01|미쓰이 가가쿠 가부시키가이샤|Capsular fine particle comprising olefinic polymer|
    CA2733560A1|2007-08-14|2009-02-19|Cellulosetek, Llc|Controlled release fertilizers and methods of manufacture|
    CN102491847B|2011-12-09|2017-05-10|邹立基|Machine for preparing soil aggregates containing chemical fertilizer|
    WO2014109252A1|2013-01-11|2014-07-17|東洋ゴム工業株式会社|Artificial soil medium|
    CN113214651A|2013-08-28|2021-08-06|杜邦东丽特殊材料株式会社|Curable silicone composition, cured product thereof, and optical semiconductor device|
    WO2017043413A1|2015-09-11|2017-03-16|住友化学株式会社|Coated granular fertilizer, method for producing coated granular fertilizer, and fertilizer composition|
    KR102111607B1|2018-03-28|2020-05-15|주식회사 엘지화학|Controlled release fertilizers|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP53000980A|JPS603040B2|1978-01-09|1978-01-09|
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